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The legs occur because of the Marangoni effect. It comes from the fact that alcohol possesses a lower surface tension than water. Liquid is mostly blending water and alcohol and also a few other sections such as sugars, tannins etc. A person swirl your wine during the glass leaving some on the side it begins to evaporate. Alcohol evaporates faster than water due to the lower boiling point and higher vapour emotional stress. The changed alcohol to water mix now has different surface tension states. The wine forms droplets in the areas of least / most resistance which fall back down the glass under unique weight.
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